Experimental investigations of the effect of alkali fluids on montmorillonite, albite and quartz

JNC TN8400 2001-008, 36 Pages, 2001/03

JNC-TN8400-2001-008.pdf:2.92MB

Research on geologic disposal of high-level radioactive waste(HLW) has been underway in many countries. Bentonite exhibiting a low permeability, high swelling property and high sorption capacity for many radioelements is proposed as a buffer material in many countlies. Recently, cementitious materials are considered as candidate matelials for the geologic disposal of high-level radioactive waste. As the pH and the Ca, Na, K contents of hyperalkaline pore water from the cementitious materials are high, this hyperalkaline pore water would alter the buffer material. The main aim of this study is to investigate the effect of alkaline pore water into the bentonite. Used materials are montmorillonite, albite and quartz composing bentonite. These minerals mixed in a constant ratio (1:1wt%) made to react to distilled water and the alkali solutions (pH11-13). These studies have been conducted at temperatures of 50 - 150C and run times of 10 - 200 day. XRD(X-ray powder diffraction) and SEM (Scanning Electron Microscopy) analyses were applied to studying the structure and quantitative data of each sample. From the result of this study, the main formed mineral of this experiment was analcime, which showed the tendency with a large amount of generation at a higher pH and temperature. Quantitative data of this study was conducted by X-ray powder diffraction method. THe order of the amount of the second analcime in each experiment is shown in the following. Montmorillonite and albite mixing test Montmorillonite test Montmorillonite and quartz mixing test Activation energies (E) using the quantitative data of each test are shown in the following. (1)Montmorillonite test : 54.9kJ/mol (2)Montmorillonite and albite mixing test : 51.9kJ/mol (3)Montmorillonite and quartz mixing test : 59.6kJ/mol

Materials properties data sheet (No. F02); Creep properties data on Mod.9Cr-1Mo steels (Base Metal)

; ; *; *; *; Yoshida, Eiichi;

PNC TN9450 91-010, 259 Pages, 1991/10

PNC-TN9450-91-010.pdf:4.55MB

In order to advancement in materials strength standard on elevated temperature design guide of the FBRs and evaluation method of materials strength behavior, this report are presented about the creep properties of Mod.9Cr-1Mo steels for steam generator, based on the R&D results obtained through the activities of material tests. Contents of the data sheet are as follows; Material : Mod.9Cr-1Mo steels (Base Metal) Plate 7 Heats (F2, F6, F7, F9, F10, NSC1, NSC2) Forging 8 Heats (F4, F5, F8, F11, VIM, ESR, F520, F550) Tube 1 Heats (F3) Test temperature : 450650C Test method : According to JIS and FBR Metallic Materials Test Method Test environment : In Air and in Sodium Number of deta : 314 points

Materials properties data sheet (No.F01); Low-cycle fatigue properties data on Mod.9Cr-1Mo steel in air and in sodium

; Hirakawa, Yasushi; Furukawa, Tomohiro; *; *; *; *

PNC TN9450 91-004, 71 Pages, 1991/07

PNC-TN9450-91-004.pdf:1.82MB

In order to advancement in materials strength standard on elevated temperature design guide of the FBRs and evaluation method of materials strength behavior, this report are presented about the low-cycle fatigue properties of Mod.9Cr-1Mo steel, based on the R&D results obtained through the sctivities of material tests. Contents of the data sheet are as follows; [Material ; Mod.9Cr-1Mo steel(SR)] F2 Heat 1,0001,00012mm(Plate) F4 Heat 1,0001,000250mm(Forging) F6 Heat 1,0001,00025mm(Plate) [Environment; In Air and in Sodium] [Test temperature ; 450, 500, 550, 600 and 650C] [Strain rate ; 0.1%/sec (10mm/mm/sec)] [Strain range ; 0.38% 1.86%] [Number of deta ; 83 points]